Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism

Nuwanthaka P. Jayaweera; Ashley E. Hall; Ashton A. Wilson; Mary E. Konkle; Kraig A. Wheeler; Radu F. Semeniuc

doi:10.1016/J.ICA.2020.119507

Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism

Nuwanthaka P. Jayaweera, Ashley E. Hall, Ashton A. Wilson, Mary E. Konkle, Kraig A. Wheeler, Radu F. Semeniuc

Eastern Illinois University

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Inorganica Chimica Acta
Volumen	506
DOI	https://doi.org/10.1016/J.ICA.2020.119507
Estado	Published - jun 1 2020

Disciplines

Medicinal-Pharmaceutical Chemistry

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10.1016/J.ICA.2020.119507Licencia: Unspecified

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https://www.sciencedirect.com/science/article/pii/S002016931931816X

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title = "Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism",

author = "Jayaweera, \{Nuwanthaka P.\} and Hall, \{Ashley E.\} and Wilson, \{Ashton A.\} and Konkle, \{Mary E.\} and Wheeler, \{Kraig A.\} and Semeniuc, \{Radu F.\}",

note = "Five ditopic bis(pyrazolyl)methane-based ligands have been prepared. * Five dinuclear Cu(II) complexes have been characterized. * The catecholase activity of these complexes was investigated. * A dual O 2/H 2O 2 oxidation mechanism has been identified.",

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language = "American English",

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T1 - Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism

AU - Jayaweera, Nuwanthaka P.

AU - Hall, Ashley E.

AU - Wilson, Ashton A.

AU - Konkle, Mary E.

AU - Wheeler, Kraig A.

AU - Semeniuc, Radu F.

N1 - Five ditopic bis(pyrazolyl)methane-based ligands have been prepared. * Five dinuclear Cu(II) complexes have been characterized. * The catecholase activity of these complexes was investigated. * A dual O 2/H 2O 2 oxidation mechanism has been identified.

PY - 2020/6/1

Y1 - 2020/6/1

UR - https://www.sciencedirect.com/science/article/pii/S002016931931816X

U2 - 10.1016/J.ICA.2020.119507

DO - 10.1016/J.ICA.2020.119507

M3 - Article

VL - 506

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -