Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring)

Daniel L. Reger; Christine A. Little; Radu F. Semeniuc; Mark D. Smith

doi:10.1016/J.ICA.2008.03.120

Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring)

Daniel L. Reger, Christine A. Little, Radu F. Semeniuc, Mark D. Smith

University of South Carolina

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Inorganica Chimica Acta
Volumen	362
DOI	https://doi.org/10.1016/J.ICA.2008.03.120
Estado	Published - ene 1 2009
Publicado de forma externa	Sí

Disciplines

Other Earth Sciences
Chemistry

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10.1016/J.ICA.2008.03.120Licencia: Unspecified

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https://www.sciencedirect.com/science/article/pii/S0020169308002867

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Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring). / Reger, Daniel L.; Little, Christine A.; Semeniuc, Radu F. et al.
En: Inorganica Chimica Acta, Vol. 362, 01.01.2009.

Producción científica › revisión exhaustiva

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title = "Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: \{HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH\}(BF4)4 (pz = pyrazolyl ring)",

author = "Reger, \{Daniel L.\} and Little, \{Christine A.\} and Semeniuc, \{Radu F.\} and Smith, \{Mark D.\}",

note = "The structure of \{HC(3,5-Me 2pz) 3Fe[μ- p-C 6H 4(CH 2OCH 2C(pz) 3) 2]Fe(3,5-Me 2pz) 3CH\}(BF 4) 4 (pz = pyrazolyl ring) contains two octahedral iron(II) centers linked by a semirigid, bitopic tris(pyrazolyl)methane ligand. The solid-state structure shows the two heteroleptic-bonded iron(II) centers are low-spin at 200 K and situated in a trans orientation with respect to the central linking arene ring.",

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language = "American English",

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T1 - Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring)

AU - Reger, Daniel L.

AU - Little, Christine A.

AU - Semeniuc, Radu F.

AU - Smith, Mark D.

N1 - The structure of {HC(3,5-Me 2pz) 3Fe[μ- p-C 6H 4(CH 2OCH 2C(pz) 3) 2]Fe(3,5-Me 2pz) 3CH}(BF 4) 4 (pz = pyrazolyl ring) contains two octahedral iron(II) centers linked by a semirigid, bitopic tris(pyrazolyl)methane ligand. The solid-state structure shows the two heteroleptic-bonded iron(II) centers are low-spin at 200 K and situated in a trans orientation with respect to the central linking arene ring.

PY - 2009/1/1

Y1 - 2009/1/1

UR - https://www.sciencedirect.com/science/article/pii/S0020169308002867

U2 - 10.1016/J.ICA.2008.03.120

DO - 10.1016/J.ICA.2008.03.120

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VL - 362

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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