Structural comparisons of silver(I) complexes of third-generation ligands built from tridentate (o-C(6)H(4)[CH(2)OCH(2)C(pz)(3)](2)) versus bidentate poly(1-pyrazolyl)methane units (o-C(6)H(4)[CH(2)OCH(2)CH(pz)(2)](2)) (pz = pyrazolyl ring).

title = "Structural comparisons of silver(I) complexes of third-generation ligands built from tridentate (o-C(6)H(4)[CH(2)OCH(2)C(pz)(3)](2)) versus bidentate poly(1-pyrazolyl)methane units (o-C(6)H(4)[CH(2)OCH(2)CH(pz)(2)](2)) (pz = pyrazolyl ring).",

author = "Reger Dl and Foley Ea and Semeniuc Rf and Radu Semeniuc",

note = "The new bitopic, bis(1-pyrazolyl)methane-based ligand o-C6H4[CH2OCH2CH(pz)2]2 (L2, pz = pyrazolyl ring) is prepared from the reaction of (pz)2CHCH2OH (obtained from the reduction of (pz)2CHCOOH with BH3.S(CH3)2) with NaH, followed by the addition of alpha,alpha'-dibromo-o-xylene. The reaction of L2 with AgPF6 or AgO3SCF3 yields \{o-C6H4[CH2OCH2CH(pz)2]2(AgPF6)\}n or \{o-C6H4[CH2OCH2CH(pz)2]2(AgO3SCF3)\}n, respectively.",

year = "2007",

month = nov,

day = "14",

doi = "10.1021/IC7017743",

language = "American English",

volume = "46",

journal = "Inorganic Chemistry",

}

TY - JOUR

T1 - Structural comparisons of silver(I) complexes of third-generation ligands built from tridentate (o-C(6)H(4)[CH(2)OCH(2)C(pz)(3)](2)) versus bidentate poly(1-pyrazolyl)methane units (o-C(6)H(4)[CH(2)OCH(2)CH(pz)(2)](2)) (pz = pyrazolyl ring).

AU - Dl, Reger

AU - Ea, Foley

AU - Rf, Semeniuc

AU - Semeniuc, Radu

N1 - The new bitopic, bis(1-pyrazolyl)methane-based ligand o-C6H4[CH2OCH2CH(pz)2]2 (L2, pz = pyrazolyl ring) is prepared from the reaction of (pz)2CHCH2OH (obtained from the reduction of (pz)2CHCOOH with BH3.S(CH3)2) with NaH, followed by the addition of alpha,alpha'-dibromo-o-xylene. The reaction of L2 with AgPF6 or AgO3SCF3 yields {o-C6H4[CH2OCH2CH(pz)2]2(AgPF6)}n or {o-C6H4[CH2OCH2CH(pz)2]2(AgO3SCF3)}n, respectively.

PY - 2007/11/14

Y1 - 2007/11/14

UR - http://europepmc.org/abstract/MED/17999497

U2 - 10.1021/IC7017743

DO - 10.1021/IC7017743

M3 - Article

VL - 46

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -