Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

Chaminda P. Gamage; Ryan C. Bailey; Ellen A. Keiter; John R. Kuczynski; Kraig A. Wheeler; Charlotte L. Stern; Douglas E. Brandt; Richard L. Keiter

doi:10.1016/J.JORGANCHEM.2015.07.017

Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

Chaminda P. Gamage
, Ryan C. Bailey
, Ellen A. Keiter
, John R. Kuczynski
, Kraig A. Wheeler
, Charlotte L. Stern
, Douglas E. Brandt
, Richard L. Keiter

Eastern Illinois University

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Journal of Organometallic Chemistry
Volumen	794
DOI	https://doi.org/10.1016/J.JORGANCHEM.2015.07.017
Estado	Published - oct 1 2015

Disciplines

Medicinal-Pharmaceutical Chemistry
Inorganic Chemistry

Acceder al documento

10.1016/J.JORGANCHEM.2015.07.017Licencia: Unspecified

Otros archivos y enlaces

https://experts.illinois.edu/en/publications/dangling-phosphine-complexes-phosphine-exchange-in-pentacarbonyl-

Citar esto

@article{1a4a287763e3482bbbb5ed725f70f3bf,

title = "Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine",

author = "Gamage, \{Chaminda P.\} and Bailey, \{Ryan C.\} and Keiter, \{Ellen A.\} and Kuczynski, \{John R.\} and Wheeler, \{Kraig A.\} and Stern, \{Charlotte L.\} and Brandt, \{Douglas E.\} and Keiter, \{Richard L.\}",

note = "Abstract The reaction of [W(CO) 5NH 2Ph] with Ph 2PCH 2PPhCH 2PPh 2 under mild conditions and stoichiometric control leads to two sets of linkage isomers: [(OC) 5W\{κ 1-PPh(CH 2PPh 2) 2\}] 6a and [(OC) 5W(κ 1- PPh 2CH 2PPhCH 2PPh 2)] 6b; [(OC) 5W\{μ-PPh 2CH 2PPh(CH 2PPh 2)\}W(CO) 5] 7a and [(OC) 5W(μ-PPh 2CH 2PPhCH 2PPh 2)W(CO) 5] 7b.",

year = "2015",

month = oct,

day = "1",

doi = "10.1016/J.JORGANCHEM.2015.07.017",

language = "American English",

volume = "794",

journal = "Journal of Organometallic Chemistry",

}

TY - JOUR

T1 - Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

AU - Gamage, Chaminda P.

AU - Bailey, Ryan C.

AU - Keiter, Ellen A.

AU - Kuczynski, John R.

AU - Wheeler, Kraig A.

AU - Stern, Charlotte L.

AU - Brandt, Douglas E.

AU - Keiter, Richard L.

N1 - Abstract The reaction of [W(CO) 5NH 2Ph] with Ph 2PCH 2PPhCH 2PPh 2 under mild conditions and stoichiometric control leads to two sets of linkage isomers: [(OC) 5W{κ 1-PPh(CH 2PPh 2) 2}] 6a and [(OC) 5W(κ 1- PPh 2CH 2PPhCH 2PPh 2)] 6b; [(OC) 5W{μ-PPh 2CH 2PPh(CH 2PPh 2)}W(CO) 5] 7a and [(OC) 5W(μ-PPh 2CH 2PPhCH 2PPh 2)W(CO) 5] 7b.

PY - 2015/10/1

Y1 - 2015/10/1

UR - https://experts.illinois.edu/en/publications/dangling-phosphine-complexes-phosphine-exchange-in-pentacarbonyl-

U2 - 10.1016/J.JORGANCHEM.2015.07.017

DO - 10.1016/J.JORGANCHEM.2015.07.017

M3 - Article

VL - 794

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -