Benzene⋯acetylene: a structural investigation of the prototypical CH⋯π interaction

Nathan W. Ulrich; Nathan A. Seifert; Rachel E. Dorris; Rebecca A. Peebles; Brooks H. Pate; Sean A. Peebles

doi:10.1039/C4CP00845F

Benzene⋯acetylene: a structural investigation of the prototypical CH⋯π interaction

Nathan W. Ulrich, Nathan A. Seifert, Rachel E. Dorris, Rebecca A. Peebles, Brooks H. Pate, Sean A. Peebles

Eastern Illinois University

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Physical Chemistry Chemical Physics
Volumen	16
DOI	https://doi.org/10.1039/C4CP00845F
Estado	Published - ene 1 2014

Disciplines

Analytical Chemistry

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10.1039/C4CP00845FLicencia: Unspecified

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https://pubs.rsc.org/en/content/articlelanding/2013/cp/c4cp00845f#!

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title = "Benzene⋯acetylene: a structural investigation of the prototypical CH⋯π interaction",

author = "Ulrich, \{Nathan W.\} and Seifert, \{Nathan A.\} and Dorris, \{Rachel E.\} and Peebles, \{Rebecca A.\} and Pate, \{Brooks H.\} and Peebles, \{Sean A.\}",

note = "The structure of a prototype CH⋯π system, benzene⋯acetylene, has been determined in the gas phase using Fourier-transform microwave spectroscopy. The spectrum is consistent with an effective C6v structure with an H⋯π distance of 2.4921(1) {\AA}. The HCCH subunit likely tilts by ∼5° from the benzene symmetry axis",

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T1 - Benzene⋯acetylene: a structural investigation of the prototypical CH⋯π interaction

AU - Ulrich, Nathan W.

AU - Seifert, Nathan A.

AU - Dorris, Rachel E.

AU - Peebles, Rebecca A.

AU - Pate, Brooks H.

AU - Peebles, Sean A.

N1 - The structure of a prototype CH⋯π system, benzene⋯acetylene, has been determined in the gas phase using Fourier-transform microwave spectroscopy. The spectrum is consistent with an effective C6v structure with an H⋯π distance of 2.4921(1) Å. The HCCH subunit likely tilts by ∼5° from the benzene symmetry axis

PY - 2014/1/1

Y1 - 2014/1/1

UR - https://pubs.rsc.org/en/content/articlelanding/2013/cp/c4cp00845f#!

U2 - 10.1039/C4CP00845F

DO - 10.1039/C4CP00845F

M3 - Article

VL - 16

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

ER -