An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph 2(O)POCh 2C9(pz) 3Ag] 2(THF) 2}(BF 4) 2: κ 2- κ 1 bimetallic, N σN π

Daniel L. Reger; Radu F. Semeniuc; Burjor Captain; Mark D. Smith

doi:10.1021/IC0501162

An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph 2(O)POCh 2C9(pz) 3Ag] 2(THF) 2}(BF 4) 2: κ 2- κ 1 bimetallic, N σN π

Daniel L. Reger, Radu F. Semeniuc, Burjor Captain, Mark D. Smith

Eastern Illinois University

University of South Carolina

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Inorganic Chemistry
Volumen	44
DOI	https://doi.org/10.1021/IC0501162
Estado	Published - may 2 2005

Disciplines

Medicinal-Pharmaceutical Chemistry
Other Earth Sciences

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10.1021/IC0501162Licencia: Unspecified

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title = "An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in \{[Ph 2(O)POCh 2C9(pz) 3Ag] 2(THF) 2\}(BF 4) 2: κ 2- κ 1 bimetallic, N σN π",

author = "Reger, \{Daniel L.\} and Semeniuc, \{Radu F.\} and Burjor Captain and Smith, \{Mark D.\}",

note = "The structure of the compound \{[Ph 2(O)POCH 2C(pz) 3Ag] 2(THF) 2\}-(BF 4) 2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal σ-type orbitals on the nitrogen donor atoms while the third pyrazolyl ring coordinates side-on to one of the silver atoms with a nitrogen-based π-type orbital.",

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AU - Reger, Daniel L.

AU - Semeniuc, Radu F.

AU - Captain, Burjor

AU - Smith, Mark D.

N1 - The structure of the compound {[Ph 2(O)POCH 2C(pz) 3Ag] 2(THF) 2}-(BF 4) 2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal σ-type orbitals on the nitrogen donor atoms while the third pyrazolyl ring coordinates side-on to one of the silver atoms with a nitrogen-based π-type orbital.

PY - 2005/5/2

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JO - Inorganic Chemistry

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