An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2: kappa2-kappa1 bimetallic, N(sigma)/N(pi) chelating.

Reger Dl; Semeniuc Rf; Burjor B; Radu Semeniuc

doi:10.1021/IC0501162

An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2: kappa2-kappa1 bimetallic, N(sigma)/N(pi) chelating.

Reger Dl, Semeniuc Rf, Burjor B, Radu Semeniuc

Eastern Illinois University

University of South Carolina

Producción científica › revisión exhaustiva

Idioma original	American English
Publicación	Inorganic Chemistry
Volumen	44
DOI	https://doi.org/10.1021/IC0501162
Estado	Published - may 2 2005

Disciplines

Other Earth Sciences
Chemistry

Acceder al documento

10.1021/IC0501162Licencia: Unspecified

Otros archivos y enlaces

https://www.ncbi.nlm.nih.gov/pubmed/15847399

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title = "An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in \{[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2\}(BF4)2: kappa2-kappa1 bimetallic, N(sigma)/N(pi) chelating.",

author = "Reger Dl and Semeniuc Rf and Burjor B and Radu Semeniuc",

note = "The structure of the compound \{[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2\}(BF4)2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal sigma-type orbitals on the nitrogen donor atoms while the third p ...",

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AU - Dl, Reger

AU - Rf, Semeniuc

AU - B, Burjor

AU - Semeniuc, Radu

N1 - The structure of the compound {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal sigma-type orbitals on the nitrogen donor atoms while the third p ...

PY - 2005/5/2

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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