Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism

TY - JOUR

T1 - Tuning the catecholase activity of bis(pyrazolyl)methane-based copper(II) complexes by substitutions of the ligand core: unraveling a dual O2/H2O2 oxidation mechanism

AU - Jayaweera, Nuwanthaka P.

AU - Hall, Ashley E.

AU - Wilson, Ashton A.

AU - Konkle, Mary E.

AU - Wheeler, Kraig A.

AU - Semeniuc, Radu F.

N1 - Five ditopic bis(pyrazolyl)methane-based ligands have been prepared. * Five dinuclear Cu(II) complexes have been characterized. * The catecholase activity of these complexes was investigated. * A dual O 2/H 2O 2 oxidation mechanism has been identified.

PY - 2020/6/1

Y1 - 2020/6/1

UR - https://www.sciencedirect.com/science/article/pii/S002016931931816X

U2 - 10.1016/J.ICA.2020.119507

DO - 10.1016/J.ICA.2020.119507

M3 - Article

VL - 506

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -