Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]

Pei Ma; Ralf Littger; Tiffany M. Smith Pellizzeri; Jon Zubieta; James T. Spencer

doi:10.1016/J.POLY.2016.02.014

Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]

Pei Ma, Ralf Littger, Tiffany M. Smith Pellizzeri, Jon Zubieta, James T. Spencer

Syracuse University

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Polyhedron
Volume	109
DOIs	https://doi.org/10.1016/J.POLY.2016.02.014
State	Published - Apr 18 2016
Externally published	Yes

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Chemistry

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@article{871cb659db3947dcbe1e54702a2d9b30,

title = "Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]",

author = "Pei Ma and Ralf Littger and Pellizzeri, {Tiffany M. Smith} and Jon Zubieta and Spencer, {James T.}",

note = "The relationship between the thermal and photochemical reaction pathways of the 10-vertex metalladecaborane complex, [ nido-6-Mn(CO) 3B 9H 13][NMe 4] ( 1), has been investigated. The reaction types observed included a nido-6 to nido-5 cage isomerization process and a nido-6 to hypercloso-metallaborane conversion through hydrogen loss and cage closure reactions.",

year = "2016",

month = apr,

day = "18",

doi = "10.1016/J.POLY.2016.02.014",

language = "American English",

volume = "109",

journal = "Polyhedron",

}

TY - JOUR

T1 - Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]

AU - Ma, Pei

AU - Littger, Ralf

AU - Pellizzeri, Tiffany M. Smith

AU - Zubieta, Jon

AU - Spencer, James T.

N1 - The relationship between the thermal and photochemical reaction pathways of the 10-vertex metalladecaborane complex, [ nido-6-Mn(CO) 3B 9H 13][NMe 4] ( 1), has been investigated. The reaction types observed included a nido-6 to nido-5 cage isomerization process and a nido-6 to hypercloso-metallaborane conversion through hydrogen loss and cage closure reactions.

PY - 2016/4/18

Y1 - 2016/4/18

UR - https://www.sciencedirect.com/science/article/pii/S0277538716000991

U2 - 10.1016/J.POLY.2016.02.014

DO - 10.1016/J.POLY.2016.02.014

M3 - Article

VL - 109

JO - Polyhedron

JF - Polyhedron

ER -

Thermal versus photochemical pathways of a manganese 10-vertex metalladecaborane: [Nido-6-Mn(CO)3B9H13][NMe4]

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