The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K

Ionel Haiduc; Radu F Semeniuc; Marius Campian; Victor Ch Kravtsov; Yurii A Simonov; Janusz Lipkowski

doi:10.1016/S0277-5387(03)00399-1

The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K

Ionel Haiduc
, Radu F Semeniuc
, Marius Campian
, Victor Ch Kravtsov
, Yurii A Simonov
, Janusz Lipkowski

Chemistry and Biochemistry

Department of Chemistry, ‘Babes-Bolyai’ University, RO-3400 Cluj-Napoca, Romania
Academy of Sciences of Moldova
Institute of Physical Chemistry of the Academy of Sciences of Poland, Kasprzaka 44/52, PL 01-244 Warsaw, Poland

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Polyhedron
Volume	22
DOIs	https://doi.org/10.1016/S0277-5387(03)00399-1
State	Published - Sep 15 2003

Disciplines

Other Earth Sciences

Access to Document

10.1016/S0277-5387(03)00399-1License: Unspecified

Cite this

Haiduc, I., Semeniuc, R. F., Campian, M., Kravtsov, V. C., Simonov, Y. A., & Lipkowski, J. (2003). The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K. Polyhedron, 22. https://doi.org/10.1016/S0277-5387(03)00399-1

The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K. / Haiduc, Ionel; Semeniuc, Radu F; Campian, Marius et al.
In: Polyhedron, Vol. 22, 15.09.2003.

Research output: Contribution to journal › Article › peer-review

Haiduc, I, Semeniuc, RF, Campian, M, Kravtsov, VC, Simonov, YA & Lipkowski, J 2003, 'The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K', Polyhedron, vol. 22. https://doi.org/10.1016/S0277-5387(03)00399-1

@article{44725be2995e469a88b2a25bc87d93eb,

title = "The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K",

author = "Ionel Haiduc and Semeniuc, \{Radu F\} and Marius Campian and Kravtsov, \{Victor Ch\} and Simonov, \{Yurii A\} and Janusz Lipkowski",

note = "The reaction between nickel(II) xanthates with tetraphenyldiphosphinoethane in molar ratio Ni:dppe 2:1 gives trinuclear complexes, [Ni 3(μ 2-S) 2(S 2COR) 2(dppe)] (R=Me, Et), whose crystal structures were investigated by single crystal X-ray diffraction. These complexes contain a trigonal bipyramidal central Ni 3S 2 core, with sulfur atoms in axial positions and nickel atoms in equatorial positions.",

year = "2003",

month = sep,

day = "15",

doi = "10.1016/S0277-5387(03)00399-1",

language = "American English",

volume = "22",

journal = "Polyhedron",

}

TY - JOUR

T1 - The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K

AU - Haiduc, Ionel

AU - Semeniuc, Radu F

AU - Campian, Marius

AU - Kravtsov, Victor Ch

AU - Simonov, Yurii A

AU - Lipkowski, Janusz

N1 - The reaction between nickel(II) xanthates with tetraphenyldiphosphinoethane in molar ratio Ni:dppe 2:1 gives trinuclear complexes, [Ni 3(μ 2-S) 2(S 2COR) 2(dppe)] (R=Me, Et), whose crystal structures were investigated by single crystal X-ray diffraction. These complexes contain a trigonal bipyramidal central Ni 3S 2 core, with sulfur atoms in axial positions and nickel atoms in equatorial positions.

PY - 2003/9/15

Y1 - 2003/9/15

UR - https://www.sciencedirect.com/science/article/pii/S0277538703003991

U2 - 10.1016/S0277-5387(03)00399-1

DO - 10.1016/S0277-5387(03)00399-1

M3 - Article

VL - 22

JO - Polyhedron

JF - Polyhedron

ER -

The reaction of nickel(II) xanthates with tetraphenyldiphosphinoethane (dppe) revisited. Formation and crystal structures of Ni3S2(S2COR)2(dppe) (R=Me, Et; dppe=Ph2PCH2CH2PPh2) at room temperature and of Ni(S2CO)(dppe) at 150 K

Disciplines

Access to Document

Other files and links

Cite this