Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring)

TY - JOUR

T1 - Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me2pz)3Fe[μ-p-C6H4(CH2OCH2C(pz)3)2]Fe(3,5-Me2pz)3CH}(BF4)4 (pz = pyrazolyl ring)

AU - Reger, Daniel L.

AU - Little, Christine A.

AU - Semeniuc, Radu F.

AU - Smith, Mark D.

N1 - The structure of {HC(3,5-Me 2pz) 3Fe[μ- p-C 6H 4(CH 2OCH 2C(pz) 3) 2]Fe(3,5-Me 2pz) 3CH}(BF 4) 4 (pz = pyrazolyl ring) contains two octahedral iron(II) centers linked by a semirigid, bitopic tris(pyrazolyl)methane ligand. The solid-state structure shows the two heteroleptic-bonded iron(II) centers are low-spin at 200 K and situated in a trans orientation with respect to the central linking arene ring.

PY - 2009/1/1

Y1 - 2009/1/1

UR - https://www.sciencedirect.com/science/article/pii/S0020169308002867

U2 - 10.1016/J.ICA.2008.03.120

DO - 10.1016/J.ICA.2008.03.120

M3 - Article

VL - 362

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -