Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthon

Daniel L. Reger; James R. Gardinier; Radu F. Semeniuc; Mark D. Smith

doi:10.1039/B301635H

Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthon

Daniel L. Reger
, James R. Gardinier
, Radu F. Semeniuc
, Mark D. Smith

University of South Carolina

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Dalton Transactions
DOIs	https://doi.org/10.1039/B301635H
State	Published - Apr 17 2003
Externally published	Yes

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Chemistry
Medicinal-Pharmaceutical Chemistry

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@article{382a081cfaa34e2ebbed7b02cf2b49c7,

title = "Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthon",

author = "Reger, \{Daniel L.\} and Gardinier, \{James R.\} and Semeniuc, \{Radu F.\} and Smith, \{Mark D.\}",

note = "The reaction between pyrazole and malonaldehyde bis(dimethylacetal) yields the first linked bis(pyrazolyl)methane ligand, CH[CH(pz)]. Reaction of this ligand with Ag(OSCF) yields [Ag\{μ-CH[CH(pz)]\}](SOCF) ( 1). In the solid state 1 contains a dimeric dication in which two ligands sandwich two silver cations forming a bicyclic sixteen-membered ring system.",

year = "2003",

month = apr,

day = "17",

doi = "10.1039/B301635H",

language = "American English",

journal = "Dalton Transactions",

}

TY - JOUR

T1 - Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthon

AU - Reger, Daniel L.

AU - Gardinier, James R.

AU - Semeniuc, Radu F.

AU - Smith, Mark D.

N1 - The reaction between pyrazole and malonaldehyde bis(dimethylacetal) yields the first linked bis(pyrazolyl)methane ligand, CH[CH(pz)]. Reaction of this ligand with Ag(OSCF) yields [Ag{μ-CH[CH(pz)]}](SOCF) ( 1). In the solid state 1 contains a dimeric dication in which two ligands sandwich two silver cations forming a bicyclic sixteen-membered ring system.

PY - 2003/4/17

Y1 - 2003/4/17

UR - https://pubs.rsc.org/en/Content/ArticleLanding/DT/2003/B301635H#!

U2 - 10.1039/B301635H

DO - 10.1039/B301635H

M3 - Article

JO - Dalton Transactions

JF - Dalton Transactions

ER -

Silver complexes of 1,1′,3,3′-tetrakis(pyrazol-1-yl)propane: the “quadruple pyrazolyl embrace” as a supramolecular synthon

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