Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

TY - JOUR

T1 - Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

AU - Gamage, Chaminda P.

AU - Bailey, Ryan C.

AU - Keiter, Ellen A.

AU - Kuczynski, John R.

AU - Wheeler, Kraig A.

AU - Stern, Charlotte L.

AU - Brandt, Douglas E.

AU - Keiter, Richard L.

N1 - Abstract The reaction of [W(CO) 5NH 2Ph] with Ph 2PCH 2PPhCH 2PPh 2 under mild conditions and stoichiometric control leads to two sets of linkage isomers: [(OC) 5W{κ 1-PPh(CH 2PPh 2) 2}] 6a and [(OC) 5W(κ 1- PPh 2CH 2PPhCH 2PPh 2)] 6b; [(OC) 5W{μ-PPh 2CH 2PPh(CH 2PPh 2)}W(CO) 5] 7a and [(OC) 5W(μ-PPh 2CH 2PPhCH 2PPh 2)W(CO) 5] 7b.

PY - 2015/10/1

Y1 - 2015/10/1

UR - https://experts.illinois.edu/en/publications/dangling-phosphine-complexes-phosphine-exchange-in-pentacarbonyl-

U2 - 10.1016/J.JORGANCHEM.2015.07.017

DO - 10.1016/J.JORGANCHEM.2015.07.017

M3 - Article

VL - 794

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -