Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

Chaminda P. Gamage; Ryan C. Bailey; Ellen A. Keiter; John R. Kuczynski; Kraig A. Wheeler; Charlotte L. Stern; Douglas E. Brandt; Richard L. Keiter

doi:10.1016/J.JORGANCHEM.2015.07.017

Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

Chaminda P. Gamage, Ryan C. Bailey, Ellen A. Keiter, John R. Kuczynski, Kraig A. Wheeler, Charlotte L. Stern, Douglas E. Brandt, Richard L. Keiter

Eastern Illinois University

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of Organometallic Chemistry
Volume	794
DOIs	https://doi.org/10.1016/J.JORGANCHEM.2015.07.017
State	Published - Oct 1 2015

Disciplines

Medicinal-Pharmaceutical Chemistry
Inorganic Chemistry

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@article{1a4a287763e3482bbbb5ed725f70f3bf,

title = "Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine",

author = "Gamage, \{Chaminda P.\} and Bailey, \{Ryan C.\} and Keiter, \{Ellen A.\} and Kuczynski, \{John R.\} and Wheeler, \{Kraig A.\} and Stern, \{Charlotte L.\} and Brandt, \{Douglas E.\} and Keiter, \{Richard L.\}",

note = "Abstract The reaction of [W(CO) 5NH 2Ph] with Ph 2PCH 2PPhCH 2PPh 2 under mild conditions and stoichiometric control leads to two sets of linkage isomers: [(OC) 5W\{κ 1-PPh(CH 2PPh 2) 2\}] 6a and [(OC) 5W(κ 1- PPh 2CH 2PPhCH 2PPh 2)] 6b; [(OC) 5W\{μ-PPh 2CH 2PPh(CH 2PPh 2)\}W(CO) 5] 7a and [(OC) 5W(μ-PPh 2CH 2PPhCH 2PPh 2)W(CO) 5] 7b.",

year = "2015",

month = oct,

day = "1",

doi = "10.1016/J.JORGANCHEM.2015.07.017",

language = "American English",

volume = "794",

journal = "Journal of Organometallic Chemistry",

}

TY - JOUR

T1 - Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

AU - Gamage, Chaminda P.

AU - Bailey, Ryan C.

AU - Keiter, Ellen A.

AU - Kuczynski, John R.

AU - Wheeler, Kraig A.

AU - Stern, Charlotte L.

AU - Brandt, Douglas E.

AU - Keiter, Richard L.

N1 - Abstract The reaction of [W(CO) 5NH 2Ph] with Ph 2PCH 2PPhCH 2PPh 2 under mild conditions and stoichiometric control leads to two sets of linkage isomers: [(OC) 5W{κ 1-PPh(CH 2PPh 2) 2}] 6a and [(OC) 5W(κ 1- PPh 2CH 2PPhCH 2PPh 2)] 6b; [(OC) 5W{μ-PPh 2CH 2PPh(CH 2PPh 2)}W(CO) 5] 7a and [(OC) 5W(μ-PPh 2CH 2PPhCH 2PPh 2)W(CO) 5] 7b.

PY - 2015/10/1

Y1 - 2015/10/1

UR - https://experts.illinois.edu/en/publications/dangling-phosphine-complexes-phosphine-exchange-in-pentacarbonyl-

U2 - 10.1016/J.JORGANCHEM.2015.07.017

DO - 10.1016/J.JORGANCHEM.2015.07.017

M3 - Article

VL - 794

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Dangling phosphine complexes: Phosphine exchange in pentacarbonyl tungsten complexes of bis(diphenylphosphinomethyl)phenylphosphine

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