Comparison of the electrochemical reductions of Ru(II) complexes of dipyrido[3,2-a:2′,3′-c]phenazine and 10,12-dimethylpteridino[6,7-f][1,10]phenanthroline-11,13(10H,12H)-dione (an alloxazine analog) in aprotic and mixed aprotic/aqueous media

TY - JOUR

T1 - Comparison of the electrochemical reductions of Ru(II) complexes of dipyrido[3,2-a:2′,3′-c]phenazine and 10,12-dimethylpteridino[6,7-f][1,10]phenanthroline-11,13(10H,12H)-dione (an alloxazine analog) in aprotic and mixed aprotic/aqueous media

AU - Olaprath, Waynie

AU - McGuire, Mark E.

N1 - We obtained and compared voltammetric and coulometric data on the ligand-centered reductions of the complexes [(bpy) 2Ru II(dppz)] 2+ (dppz = dipyrido[3,2-a:2′,3′-c]phenazine) and [(bpy) 2Ru II(pptd)] 2+ (pptd = 10,12-dimethylpteridino[6,7-f][1,10]phenanthroline-11,13( 10H, 12H)-dione; an alloxazine analog) in both aprotic (DMSO) and protic (80 mol% H 2O/DMSO pH ∼6.6) media.

PY - 2012/3/30

Y1 - 2012/3/30

UR - https://www.sciencedirect.com/science/article/pii/S0020169311008358

U2 - 10.1016/J.ICA.2011.10.025

DO - 10.1016/J.ICA.2011.10.025

M3 - Article

VL - 383

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -