An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph 2(O)POCh 2C9(pz) 3Ag] 2(THF) 2}(BF 4) 2: κ 2- κ 1 bimetallic, N σN π

TY - JOUR

T1 - An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph 2(O)POCh 2C9(pz) 3Ag] 2(THF) 2}(BF 4) 2: κ 2- κ 1 bimetallic, N σN π

AU - Reger, Daniel L.

AU - Semeniuc, Radu F.

AU - Captain, Burjor

AU - Smith, Mark D.

N1 - The structure of the compound {[Ph 2(O)POCH 2C(pz) 3Ag] 2(THF) 2}-(BF 4) 2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal σ-type orbitals on the nitrogen donor atoms while the third pyrazolyl ring coordinates side-on to one of the silver atoms with a nitrogen-based π-type orbital.

PY - 2005/5/2

Y1 - 2005/5/2

UR - https://miami.pure.elsevier.com/en/publications/an-unprecedented-coordination-mode-of-the-trispyrazolylmethane-do

UR - http://cat.inist.fr/?aModele=afficheNcpsidt=16753905

U2 - 10.1021/IC0501162

DO - 10.1021/IC0501162

M3 - Article

VL - 44

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -