An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2: kappa2-kappa1 bimetallic, N(sigma)/N(pi) chelating.

TY - JOUR

T1 - An unprecedented coordination mode of the tris(pyrazolyl)methane donor set in {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2: kappa2-kappa1 bimetallic, N(sigma)/N(pi) chelating.

AU - Dl, Reger

AU - Rf, Semeniuc

AU - B, Burjor

AU - Semeniuc, Radu

N1 - The structure of the compound {[Ph2(O)POCH2C(pz)3 Ag]2 (THF)2}(BF4)2 (pz = pyrazolyl ring) revealed a new coordination mode for the tris(pyrazolyl)methane donor set: two pyrazolyl rings bridging the same two silvers atoms using normal sigma-type orbitals on the nitrogen donor atoms while the third p ...

PY - 2005/5/2

Y1 - 2005/5/2

UR - https://www.ncbi.nlm.nih.gov/pubmed/15847399

U2 - 10.1021/IC0501162

DO - 10.1021/IC0501162

M3 - Article

VL - 44

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -